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SPECTRAL ANALYSIS OF Tb3+ /Sm3+ ION DOPED IN TeO2 - B2O3 - ZnO - Na2O GLASS
Corresponding Author(s) : Tran Thi Hong
UED Journal of Social Sciences, Humanities and Education,
Vol. 7 No. 1 (2017): UED JOURNAL OF SOCIAL SCIENCES, HUMANITIES AND EDUCATION
Abstract
The Tb3+/Sm3+ doped glass with its composition of TeO2 -B2O3 - ZnO - Na2O - RE2O3 (RE=Tb, Sm) has been synthesized via the melt quenching method; their luminescence properties are investigated through excitation and emission spectra. The photoluminescence spectrum of the Tb3+ ion singly doped glass shows a prominent green emission at 543nm (5D4→7F5) with an excitation of λexc=379nm (7F6→5G6). The photoluminescence spectrum of the Sm3+ doped glass reveals a bright red emission at 600nm (4G5/2→6H7/2) with an excitation of 401nm (6H5/2→4F7/2). The Tb3+/Sm3+ co-doped glass with an excitation of λexc=379nm exhibits an energy transfer from Tb3+ to Sm3+. This energy transfer process is explained by means of schemata showing energy levels.
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[1] A. Agarwal, I. Pal, S. Sanghi and M.P. Aggarwal (2009), Judd–Ofelt parameters and radiative properties of Sm3+ ions doped zinc bismuth borate glasse, Opt. Mater. 32, pp.339-344.
[2] S. Arunkumar, K.V. Krishnaiah, K. Marimuthu (2013), Structural and luminescence behavior of lead fluoroborate glasses containing Eu3+ ions, Physica B 416, pp.88-100.
[3] P. Babu, Jang Kyoung Hyuk, Kim Eun Sik, Shi Liang, R. Vijaya, V. Lavín, C.K. Jayasankar, Seo Hyo Jin (2010), Optical properties and energy transfer of Dy3+ - doped transparent oxyfluoride glasses and glass - ceramics, J. Non - Cryst. Solids 356, pp.236-243.
[4] H. Guo, H. Zhang, J.J. Li, F. Li (2010), Blue-white-green tunable luminescence from Ba2Gd2Si4O13: Ce3+, Tb3+ phosphors excited by ultraviolet light, Opt. Express 18, pp.27257-27262.
[5] T.T.Hong, P.T.Dung, V.X. Quang (2016), Energy transfer process Eu3+ ions doped in Tellurite glass, J. Electro. Mater. 45, pp.2569-2575.
[6] T.T. Hong, P.D.H.Yen, V.X.Quang, P.T.Dung (2015), Luminescence properties of Ce/Tb/Sm co-doped Tellurite glass for White Leds application, Mater. Trans. 56, 1419-1421.
[7] A.Biswas, G.S.Maciel, R.Kapoor, C.S. Friend, P.N.Prasad (2003), Er3+-doped multicomponent sol-gel-processed silica glass for optical signal amplification at 1.5 μm, Appl. Phys. Lett., 82, pp.2389-2391.
[8] K. Maheshvaran, P.K. Veeran, K. Marimuthu (2013), Structural and optical studies on Eu3+ doped boro-tellurte glasses, Solid State Sci. 17, pp.54-62.
[9] O. Ravi, C.M. Reddy, L. Manol, B.D.P. Raju (2012), Structural and optical studies of Sm3+ ions doped niobium borotellurite glasses, J. Mol. Struct. 1029, pp.53-59.
[10] W. Stambouli, H. Elhouichet, B. Gelloz, M. Ferid, N. Koshida (2012), Energy transfer induced Eu3+ photoluminescence enhancement in tellurite glass, J. Lumin. 132, pp.205-209.
[11] Tao Lili, H. Tsang Yuen, Zhou Bo, Richards Billy, Jha Animesh (2012), Enhanced 2.0 μm emission and energy transfer in Yb3+/Ho3+/Ce3+ triply doped tellurite glass, J. Non - Cryst. Solids 356, pp.1644-1648.
[12] G. Lakshminarayana, R. Yang, J.R. Qiu, M.G. Brik, G.A. Kumar, I.V. Kityk (2009), White light emission from Sm3+/Tb3+ codoped oxyfluoride aluminosilicate glasses under Uv light excitation, J. Phys. D: Appl. Phys. 42, pp.015414-015426.
[13] A.D. Pearson, G.E. Peterson, W.R. Northover (1966), Tb3+ fluorescence and nonradiative energy transfer from Gd3+ to Tb3+ in borate glass, J. Appl. Phys. 37, pp.729-734.
[14] T. Tsuboi (2004), Optical properties os Ce3+/Tb3+ -codoped borosilicate glasses, Eur. Phys. J. Appl. Phys. 26, pp.95-101.
[15] Wei RongFei, Zhang Hao, Li Fang, Guo Hai (2012), Blue-white-green tunable luminescence of Ce3+, Tb3+ co-doped Sodium Silicate glasses for White Leds, J. Am. Ceram. Soc. 95, pp.34-36.
[16] Z. Xu, Y. Li, Z. Liu, D. Way (2005), Uv and X-ray excited luminescence of Tb3+-doped ZnGa2O4 phosphorts, J.Alloys Compd. 391, pp.202-205.
[17] Zhang Mengfei, Liang Yujun, Tang Rui, Yu Dongyan, Tong Miaohui, Wang Qiang, Zhu Yingli, Wu Xingya, Li Guogang (2014), Highly efficient Sr3Y2(Si3O9)2:Ce3+, Tb3+/Mn2+/Eu2+ phosphors for white LEDs: structure refinement, color tuning and energy transfer, RSC Adv. 4, pp.40626-40637.
[18] Ravi Babu Y.N.Ch., Sree Ram Naik P., Vijaya Kumar K., Rajesh Kumar N., Suresh Kumar A. (2012), Spectral investigations of Sm3+ doped lead bismuth magnesium borophosphate glasses, J. Quant. Spectrosc. Radiat. Transfer 113, pp.1669-1675.
[19] K. Maheshvaran, K. Linganna, K. Marimuthu (2011), Composition dependent structural and optical properties of Sm3+ doped bora-tellurite glasses, J. Lumin. 131, pp.2746-2753.
[20] S.S. Sundari, K. Marimuthu, M. Sivaraman, S.S. Babu (2010), Composition dependent structural and optical properties of Sm3+ - doped sodium borate and sodium fluoroborate glasses, J.Lumin.130, pp.1313-1319.
[21] A. Thulasiramudu, S. Buddhudu (2007), Optical characterization of Sm3+ and Dy3+: ZnOPbO-B2O3 glasses, Spectrochim. Acta A 67, pp.802-807.
[22] L. Zhu, C. Zuo, Z. Luo, A. Lu (2010), Photoluminescence of Dy3+ and Sm3+: SiO2- Al2O3-LiF-CaF2 glasses, Physica B 405, pp.4401-4406.
[23] A. Bahadur, Y. Dwivedi, S.B. Rai (2014), Enhanced luminescence and energy transfer study in Tb:Sm codoped lead fluorotellurite glass, Spectrochim. Acta, Part A: Mol. Spect., 118, pp.177-181.
[24] Chen Quiaoqiao, Dai Nengli, Liu Zijun, Chu Yingbo, Ye Baoyuan, Li Haiqing, Peng Jinggang, Jiang Zuowen, Li Jinyan (2014), White light luminous properties and energy transfer mechanism of rare earth ions in Ce3+/Tb3+/Sm3+ co-doped glasses, Appl. Phys. A 115, pp.1159-1166.
[25] C.P. Reddly, V. Naresh, R. Ramaraqhavulu, B.H. Rudramadevi, K.T. Reddy, S. Buddhudu (2015), Energy transfer based based emission analysis of (Tb3+, Sm3+): lithium zinc phosphate glasses, Spectrochim. Acta, Part A 144, pp.68-75.
[26] L.G.Van Uitert, E.F. Dearborn, J.J. Rubin (1996), Mechanisms of energy transfer involving trivalent Tb and Sm, J. Chem. Phys. 45, pp.1578-1582.