Date Log
RESEARCHING STRUCTURE AND MAGNETIC PROPERTIES OF PEROVSKITE REMnO3 (RE=La,Nd,Pr)
Corresponding Author(s) : Nguyen Thi My Duc
UED Journal of Social Sciences, Humanities and Education,
Vol. 6 No. 3 (2016): UED JOURNAL OF SOCIAL SCIENCES, HUMANITIES AND EDUCATION
Abstract
This paper presents our study on the production of a sample system of perovskite manganites REMnO3 with rare earth ions RE=La,Nd,Pr respectively by means of a solid-state reaction technology. The structure and magnetic properties have been investigated. The crystal structure of LaMnO3 is cubic, whereas the crystal structures of NdMnO3 and PrMnO3 are orthorhombic. We have investigated the dependence of the magnetic temperature on the samples’ temperature and the magnetic field. In addition, we have calculated the Curie and Weiss temperature as well as Curie constants of the samples. We have discovered other transition at 15.3 K and 42.5 K for the NdMnO3 sample. We have compared the magnetic properties of the samples, thereby discussing the impact of rare earth ions on the properties of the sample systems.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
-
[1] Huỳnh Đăng Chính (2003), Tổng hợp, cấu trúc và tính chất điện - từ của một số Perovskite bằng phương pháp Sol-Gel, Luận án tiến sĩ hóa học, Trường Đại học Bách khoa Hà Nội.
[2] PGS.TS Nguyễn Ngọc Long (2007), Vật lý chất rắn, NXB Đại học Quốc gia Hà Nội.
[3] Nguyễn Thị Thủy (2014), Nghiên cứu tính chất điện, từ của một số perovskite nhiệt điện, Luận án tiến sĩ Vật lý, Khoa Vật lý, ĐH. Khoa học Tự nhiên, ĐHQGHN.
[4] Ngô Hồ Quang Vũ (2010), Giới thiệu về phương pháp SEM, TP. Hồ Chí Minh.
[5] Goldschmidt V. (1958), Geochemistry, Oxford University press.
[6] Hemberger J. et al. (2003), “Magnetic and thermodynamic properties of RMnO3 (R = Pr, Nd)”, arXiv: cond-mat, 1, 0311170.
[7] Hong F. et al. (2012), “Positive and negative exchange bias effects in the simple perovskite manganite NdMnO3”, Applied Physics Letters, 101(10), pp. 102411-102415.
[8] Jativa J. et al. (2012), “Hydrothermal synthesis, magnetic susceptibility, electrical transport andvibrational order of the polycrystalline structure La0.5Ba0.5MnO3”, Revista Mexicana de Fisica S, 58(2), pp. 19–23.
[9] Jeffrey J. et al. (2004), “Synthesis of Single-Crystalline La1-xBaxMnO3 Nanocubes with Adjustable Doping Levels”, Nano Letters, 4(8), pp. 1547-1550.
[10] Kotomin E.A. et al. (2006), “First principles calculations of the atomic and electronic structure of LaMnO3 (001) surface”, Computer Modelling and New Technologies, 10(3), pp. 29-40.
[11] Lim K.P. et al. (2009), “Effect of Divalent Ions (A = Ca, Ba and Sr) Substitution in La-Mn-O Magnetic and Electrical Transport Properties”, American Journal of Applied Sciences 6 (6), pp. 1153-1157.
[12] Maris G. et al (2004), “Effect of ionic size on the orbital ordering transitionin RMnO3+ δ”, New Journal of Physics (6), pp. 153.
[13] Maryam Shaterian.et al. (2014), “Synthesis, characterization and photocatalytic activity of LaMnO3 nanoparticles”, Applied Surface Science, 218, pp. 213-217.
[14] Mota D.A. et al. (2014), “Dynamic and structural properties of orthorhombic rare-earth manganites under high pressure”, Appl.Phys, 92, pp. 7355-7361.
[15] Nagaev E.L. (1983), Physics of magnetic Semiconductor, Mir Pub, Moscow.
[16] Nguyen Hoang Luong, (2008), “Room-temperature large magnetocaloric effect in perovskites (La1-xNdx)0.7Sr0.3MnO3”, VNU Journal of Science, Mathematics – Physics, 24, pp. 30-35.
[17] Pecharsky V.K., K.A. Gschneidner (1997), J. Magn. Magn. Mater, 167 L179.
[18] Phan Manh Huong, Seyong Cho – yu (2006), “Review of the magnetocaloric effect in manganite materials”, Journal of Magnetism and Magnetic Materials, 308, pp. 325–340
[19] Pradhan A.K. et al. (2008), “Synthesis and magnetic characterizations of manganite-base composite nanoparticles for biomedical applications”, J. App. Phys. 103, 07F704.
[20] Rajee Ranjan (2008), “Subtle Structural Distortions in Some Dielectric Perovskite”, Journal of the Indian Institute of Sciences, 88(2), pp. 211.
[21] Rao C. N. R. (1997), “Charge Ordering in Manganates”, Science 276, pp. 911-912.
[22] Rob Janes and Elaine Moore (2004), Handbook: Metal - Ligand Bonding, The Open University, UK.
[23] Rowe D. M. (1995), CRC Handbook of thermoelectrics, CRC Press.
[24] Santhosh Kumar B. et al. (2015), “Electrical property of Half Metallic Ferromagnet Pr0.95Mn0.939O3”, pp. 1060.
[25] Satpathy S. et al. (1996), “Advances in Chemistry”, J. Appl. Phys, 79, pp 45-55.
[26] Tang F.L. et al. (2009), “Structural relaxation and Jahn-Teller distortion of LaMnO3 (001) surface”, Surface Science, 603(6), pp. 949-954.
[27] Tejuca, Luis G. (1993), Properties and applications of perovskite-type oxides, New York, Dekker.
[28] Tishin A.M. (1999), Handbook of Magnetic Materials, ed. K.H. J. Buschow, North – Holland, Amsterdam, 12, pp. 395.
[29] Tokeer Ahmad. et al. (2013), “Low-temperature synthesis, structural and magnetic properties of self-dopant LaMnO3+ nanoparticles from a metal-organic polymeric precursor ”, Materials Research Bulletin, 48, pp. 4723–4728.
[30] Wong Jen Kuen. et al. (2012), “Effect of Rare Earth Elements Substitution in La site forLaMnO3 Manganites”, 86, pp. 80-86.
[31] Yakhmi J.V. et al. (2000), “Does the LaMnO3 phase accept Ce-doping?”, Journal of Physics: Condensed Matter, 12(47) L719.
[32] Zener Calarence (1951), Phys. Rev. B, 82, pp. 403.